MERCK 100201 Phenol EMPROVE® ESSENTIAL Ph Eur,JP,USP

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Stok Kodu
100201.9025
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Description
Catalogue Number 100201
Synonyms Hydroxybenzene, Carbolic acid
Description Phenol
Product Information
CAS number 108-95-2
EC index number 604-001-00-2
EC number 203-632-7
Grade Ph Eur,JP,USP
Hill Formula C₆H₆O
Chemical formula C₆H₅OH
Molar Mass 94.11 g/mol
HS Code 2907 11 00
Structure formula Image
Physicochemical Information
Density 1.07 g/cm3 (20 °C)
Explosion limit 1.3 - 9.5 %(V)
Flash point 81 °C
Ignition temperature 595 °C
Melting Point 40.8 °C
pH value 5 (50 g/l, H₂O, 20 °C)
Vapor pressure 0.2 hPa (20 °C)
Bulk density 620 kg/m3
Solubility 84 g/l
Toxicological Information
LD 50 dermal LD50 Rat 660 mg/kg
Safety Information according to GHS
Hazard Pictogram(s)


Hazard Statement(s) H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
H314: Causes severe skin burns and eye damage.
H341: Suspected of causing genetic defects.
H373: May cause damage to organs through prolonged or repeated exposure.
Precautionary Statement(s) P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Signal Word Danger
RTECS SJ3325000
Storage class 6.1A Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK WGK 2 water endangering
Disposal 9
Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).
Safety Information
Hazard Symbols Corrosive
Toxic
Categories of danger toxic, corrosive, mutagenic
R Phrase R 23/24/25-34-48/20/21/22-68
Toxic by inhalation, in contact with skin and if swallowed.Causes burns.Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.Possible risk of irreversible effects.
S Phrase S 24/25-26-28-36/37/39-45
Avoid contact with skin and eyes.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.After contact with skin, wash immediately with plenty of soap and water.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Storage and Shipping Information
Storage Store at +15°C to +25°C.
Transport Information
Declaration (railroad and road) ADR, RID UN 1671 , 6.1, II
Declaration (transport by air) IATA-DGR UN 1671 , 6.1, II
Declaration (transport by sea) IMDG-Code UN 1671 , 6.1, II
Specifications
Assay (bromatometric) 99.0 - 100.5 %
Assay (bromatometric, calc. on anhydrous substance) 99.0 - 100.5 %
Identity (coloring 1) passes test
Identity (coloring 2) passes test
Identity (precipitate) passes test
Appearance colourless or faintly pink or faintly yellowish crystals or crystalline masses, deliquescent
Appearance of solution (67 g/l, water) clear and not more intensely coloured than reference solution B6
Acidic substances passes test
Solidification temperature ≥ 39.5 °C
Benzene (HS-GC) ≤ 2 ppm
Methanol (HS-GC) ≤ 3000 ppm
Acetone (HS-GC) ≤ 2 ppm
Anisole ≤ 10 ppm
Cumene (HS-GC) ≤ 70 ppm
Methylisobutylketone (HS-GC) ≤ 2 ppm
Other residual solvents (ICH (Q3C)) excluded by manufacturing process
Residue on evaporation ≤ 0.05 %
Water (according to Karl Fischer) ≤ 0.5 %
Residues of metal catalysts or metal reagents acc. to EMEA/C HMP/SWP/4446/2000 are not likely to be present.
Corresponds to Ph Eur, JP, USP
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MERCK 100201 Phenol EMPROVE® ESSENTIAL Ph Eur,JP,USP

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