MERCK 106357 Sodium disulfite (sodium metabisulfite) EMPROVE® ESSENTIAL Ph Eur,BP,JP,NF,E 223

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106357.5000
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Description
Catalogue Number 106357
Synonyms Sodium metabisulfite, Sodium pyrosulfite, Disulfite, Pyrosulfite
Product Information
CAS number 7681-57-4
EC index number 016-063-00-2
EC number 231-673-0
Grade Ph Eur,BP,JP,NF,E 223
Hill Formula Na₂O₅S₂
Molar Mass 190.11 g/mol
HS Code 2832 10 00
Physicochemical Information
Density 2.36 g/cm3 (20 °C)
Melting Point 150 °C (decomposition)
pH value 3.5 - 5 (50 g/l, H₂O, 20 °C)
Bulk density 1000 - 1200 kg/m3
Solubility 650 g/l
Toxicological Information
LD 50 oral LD50 Rat 1540 mg/kg
LD 50 dermal LD50 Rat > 2000 mg/kg
Safety Information according to GHS
Hazard Pictogram(s)

Hazard Statement(s) H302: Harmful if swallowed.
H318: Causes serious eye damage.
EUH031: Contact with acids liberates toxic gas.
Precautionary Statement(s) P280: Wear eye protection.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P313: Get medical advice/ attention.
Signal Word Danger
RTECS UX8225000
Storage class 10 - 13 Other liquids and solids
WGK WGK 1 slightly water endangering
Disposal 6
Sulfides and sulfites as well as other reducing substances, inorganic cyanides and isonitriles: Stir into sodium hypochlorite solution (Cat. No. 105614) and, if necessary, leave to react for several days. Caution: some substances may show a violent reaction! Draw off any toxic or flammable gases that may be formed. Excess oxidant should be neutralized with sodium thiosulfate (Cat. No. 106513). Container D or E.
Safety Information
Hazard Symbols Harmful
Categories of danger harmful, irritant
R Phrase R 22-31-41
Harmful if swallowed.Contact with acids liberates toxic gas.Risk of serious damage to eyes.
S Phrase S 26-39-46
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear eye/face protection.If swallowed, seek medical advice immediately and show this container or label.
Storage and Shipping Information
Storage Store at +5°C to +30°C.
Transport Information
Declaration (railroad and road) ADR, RID Kein Gefahrgut
Declaration (transport by air) IATA-DGR No Dangerous Good
Declaration (transport by sea) IMDG-Code No Dangerous Good
Specifications
Assay (iodometric) 97.0 - 100.0 %
Assay (iodometric, SO₂) 65.4 - 67.4 %
Identity passes test
Appearance of solution passes test
pH-value (5 %; water) 3.5 - 5.0
Chloride (Cl) ≤ 0.01 %
Heavy metals (as Pb) ≤ 0.001 %
Thiosulfate (S₂O₃) ≤ 0.05 %
As (Arsenic) ≤ 0.0002 %
Fe (Iron) ≤ 0.0005 %
Hg (Mercury) ≤ 0.0001 %
Pb (Lead) ≤ 0.0002 %
Se (Selenium) ≤ 0.0003 %
Residual solvents (Ph.Eur./USP/ICH) excluded by the manufacturing process
Residues of metal catalysts or metal reagents acc.to EMEA/CH MP/SWP/4446/2000
are not likely to be present.
Conforms to the purity criteria on food additives according to the current European Commission Regulation.
Conforms to Ph Eur, BP, JP, NF, E223
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MERCK 106357 Sodium disulfite (sodium metabisulfite) EMPROVE® ESSENTIAL Ph Eur,BP,JP,NF,E 223

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